87898-85-9

Basic information

• Product Name: N,N-dimethyl-α,β-dioxophenylpropanamide
• Synonyms: N,N-dimethyl-α,β-dioxophenylpropanamide
• CAS NO: 87898-85-9
• Molecular Weight: 205.213
• Mol File: 87898-85-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: N,N-dimethyl-α,β-dioxophenylpropanamide(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-dimethyl-α,β-dioxophenylpropanamide(87898-85-9)
• EPA Substance Registry System: N,N-dimethyl-α,β-dioxophenylpropanamide(87898-85-9)

Safety Data

• Hazardous Substances Data: 87898-85-9(Hazardous Substances Data)

Upstream product

• 94-02-0 ethyl 3-oxo-3-phenylpropionate 
• 18871-71-1 N,N-dimethyl 3-oxo-3-phenyl-propanamide 
• 25726-04-9 phenylglyoxylyl chloride 
• 479486-96-9 N,N-dimethyl (trimethylsilyl)methanamide 
• 87898-83-7 2-Brom-N,N-dimethyl-3-oxo-3-phenylpropanamid 

Downstream Products

• 87898-87-1 N,N-Dimethyl-2,3-dioxo-3-phenylpropanthioamid 

Relevant articles and documents

Direct Synthesis of Vicinal Tricarbonyl Amides by Coupling of α-Oxo Acid Chlorides with Carbamoylsilanes

A convenient synthetic method for vicinal tricarbonyl amides by the cross-coupling reaction of α-oxo acid chlorides with carbamoylsilanes is developed. The reaction tolerates a broad range of substituents on the amido nitrogen of carbamoylsilanes, and directly affords good yields of vicinal tricarbonyl amides under mild conditions without use of oxidants. The reaction of carbamoylsilanes with oxalyl chloride has also been explored, and is accompanied by decarbonylation to give vicinal tricarbonyl amides.

Preparation of New Vicinal Tricarbonyl Compounds and Some of Their Sulfur Analogues

Mesoxalamides 5, benzoylglyoxylamides 19, and pivaloylglyoxylamides 26 are prepared from the corresponding malonamides 4, benzoylacetamides 17 and pivaloylacetamides 24, respectively, by suitable oxidation reactions.Some of the sulfur analogues of 5,19, a