87908-14-3Relevant articles and documents
TRANSPOSITION DE L'ATOME D'AZOTE DE DIALKYLAMINOPENTOPYRANOSIDES; MISE EN EVIDENCE DE SELS D'AZIRIDINIUM INTERMEDIAIRES
Picq, D.,Cottin, M.,Anker, D.,Pacheco, H.
, p. 1797 - 1802 (2007/10/02)
Methyl pyranosides with dimethylamino and sulfonyloxy groups in trans relationship undergo rearrangement with participation of the dimethylamino group.This rearrangement results in a 1,2-shift of the nitrogen function which is assumed to be concerted in a