87910-62-1Relevant academic research and scientific papers
Mitsunobu acylation of sterically congested secondary alcohols by N,N, N′,N′-tetramethylazodicarboxamide-tributylphosphine reagents
Tsunoda, Tetsuto
, p. 2529 - 2530 (1995)
Four secondary alcohols of different steric environment reacted with five carboxylic acids of different acidity in the presence of N,N,N′,N′-tetramethylazodicarboxamide and tributylphosphine to give the corresponding epi-esters in better yield than with diethyl azodicarboxylate-triphenylphosphine in most cases. Of special merit is the combination of the new reagent system with p-methoxybenzoic acid to achieve complete inversion of sterically congested secondary alcohols.
OXIDATION OF BENZYL ETHER TO BENZOATE BY OZONE
Hirama, Masahiro,Shimizu, Mitsuaki
, p. 781 - 786 (2007/10/02)
Ozoniation of benzyl ethers at low temperatures in acetone or methanol solvent smoothly gave the corresponding benzoates in good yields.
