87919-77-5Relevant academic research and scientific papers
DIE CHEMIE DER SCHWEREN CARBEN-ANALOGEN R2M, M=Si, Ge, Sn. XI. REAKTIONEN VON THERMISCH ERZEUGTEM DIMETHYLSILYLEN MIT C-C-MEHRFACHBINDUNGEN
Appler, Hubertus,Neumann, Wilhelm P.
, p. 261 - 272 (2007/10/02)
Phenylated alkynes from 1,4-disila-cyclohexadienes (VIII-X) with thermally generated Me2Si (200 deg C).Bulky substituents (CMe3, SiMe3) prevent the addition.The strained cycloalkyne 3,3,6,6-tetramethyl-1-thia-cycloheptyne-4 (XI), however, yields the known silirene XII (2,2,6,6,8,8-hexamethyl-8-sila-4-thia-bicycloΔ1.7>octane); its transformation to the 1,4-disila-cyclohexadiene is prevented by steric effects.Thermally stable 1,3-dienes give, depending on their substitution pattern, 1-silacyclopentenes-2 or -3.A mechanism is proposed giving the observed products via an initial 1,2-addition.
REACTIONS OF SILYLENES WITH 1,4-DIPHENYL-1,3-BUTADIENE AND 1-METHYL-1,2,3,4,5-PENTAPHENYLSILOLE. A NOVEL SILYLENE-SILYLENE EXCHANGE REACTION
Sakurai, Hideki,Kobayashi, Yoshiteru,Sato, Ryuji,Nakadaira, Yasuhiro
, p. 1197 - 1200 (2007/10/02)
Thermally generated dimethylsilylene reacts with 1,4-diphenyl-1,3-butadiene to give 1,1-dimethyl-4,5-diphenyl-1-silacyclo-2-pentene.A mechanism involving homolytic C-C bond cleavage of the intermediate vinylsilacyclopropane is suggested.Dimethylsilylene also undergoes a novel silylene-silylene exchange reaction with 1-methyl-1,2,3,4,5-pentaphenylsilole.
