87921-28-6

Basic information

• Product Name: R-(+)-4-methyl-6-(tert-butyldimethylsiloxy)-1-hexyl benzenesulphonate
• Synonyms: R-(+)-4-methyl-6-(tert-butyldimethylsiloxy)-1-hexyl benzenesulphonate
• CAS NO: 87921-28-6
• Molecular Weight: 386.628
• Mol File: 87921-28-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: R-(+)-4-methyl-6-(tert-butyldimethylsiloxy)-1-hexyl benzenesulphonate(CAS DataBase Reference)
• NIST Chemistry Reference: R-(+)-4-methyl-6-(tert-butyldimethylsiloxy)-1-hexyl benzenesulphonate(87921-28-6)
• EPA Substance Registry System: R-(+)-4-methyl-6-(tert-butyldimethylsiloxy)-1-hexyl benzenesulphonate(87921-28-6)

Safety Data

• Hazardous Substances Data: 87921-28-6(Hazardous Substances Data)

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 97345-71-6 (+)-(6R)-8-tert-butyldimethylsilyloxy-2,6-dimethyloct-2-ene 
• 1117-61-9 (3R)-citronellol 
• 87921-27-5 R-(+)-4-methyl-6-(tert-butyldimethylsiloxy)-1-hexanol 
• 98-09-9 benzenesulfonyl chloride 

Relevant articles and documents

Enamines of 2,2-bis(ethylthio)ethanal: a convenient route to γ-keto crotonate derivatives

A new α-oxoaldehyde reagent, 2,2-bis(ethylthio)ethanal 1, has been prepared in high yield from ethanedial.Alkylation of the potassium salt of the enamines of 1 with various alkylating agents followed by in situ hydrolysis of the intermediate imine afforded high yields of the alkylation products of 1.This new reagent was used in the synthesis of a chiral potential precursor of the macrocyclic fragment of cytochalasins A,B, and F, as well as in the syntheses of the physiologically active diolides pyrenophorin and norpyrenophorin.