87947-50-0Relevant academic research and scientific papers
REACTION OF SULFOXIDES OF THE SULFOLANE SERIES WITH THIONYL CHLORIDE
Tolstikov, G. A.,Novitskaya, N. N.,Shul'ts, E. E.
, p. 1447 - 1452 (2007/10/02)
A new reaction in the sulfolane series, involving the formation of 3-alkylthio-4-oxo-2-sulfolenes from trans-3-alkylsulfinyl-4-hydroxysulfolanes by the action of thionyl chloride, was discovered and investigated.The high reactivity of the new ketones in diene synthesis and condensation with aromatic aldehydes was demonstrated.Sulfolane-sulfoxides with various structures enter into the Pummerer reaction.
