87953-00-2Relevant academic research and scientific papers
THE REACTIONS OF α-ALKOXYALLYLPHOSPHINE OXIDE YLIDES WITH SILICON, SULPHUR AND PHOSPHORUS ELECTROPHILES
Devchand, Dipak K.,Murray, Alistair W.,Smeaton, Elizabeth
, p. 4635 - 4638 (2007/10/02)
Anions (2), derived from α-methoxyallylphosphine oxides (1), react with silicon, sulphur and phosphorus electrophiles in a highly regioselective fashion to give the products of γ-attack.
The Reactive Behaviour of Methyl Substituted Propenoyldiphenylphosphanes and their Oxides
Lindner, Ekkehard,Tamoutsidis, Efstathios
, p. 3141 - 3150 (2007/10/02)
The action of RC(O)Cl (1a - e) on (CH3)3SiPPh2 generates only the propenoyldiphenylphosphanes RC(O)PPh2 2c - e, in the case of 2a, b polymerization and decomposition, respectivel
Synthesis, Structure, and Isomerism of Stable Diphosphorylated Enols
Lindner, Ekkehard,Tamoutsidis, Efstathios,Hiller, Wolfgang,Fawzi, Riad
, p. 3151 - 3163 (2007/10/02)
Under addition of the intermediary formed HP(O)Ph2 to the double bond of 1a - c the hydrolysis of the unsaturated acyldiphenylphosphane oxides R1R2C=CR3C(O)P(O)Ph2 (1a - c) yields the E-isomeric phosphorylated enols Ph2(O)
