87964-47-4Relevant academic research and scientific papers
FORMATION OF A 1,2,4-DIOXAZOLIDINE BY ELECTRON-TRANSFER PHOTOOXYGENATION OF 1-BUTYL-2,3-DIPHENYLAZIRIDINE
Schaap, A. Paul,Prasad, Girija,Gagnon, Steven D.
, p. 3047 - 3050 (1983)
Electron-transfer photooxygenation of 1-butyl-2,3-diphenylaziridine with 9,10-dicyanoanthracene in oxygen-saturated acetonitrile yields 4-butyl-3,5-diphenyl-1,2,4-dioxazolidine.This peroxide is surprisingly stable in nonpolar solvents decomposing to benzaldehyde and N-butylbenzamide upon heating to 100 deg C in benzene.Treatment with triphenyl phosphine yields benzaldehyde and N-butyl-1-phenylmethanimine.
FORMATION OF 1,2,4-DIOXAZOLIDINES BY ELECTRON-TRANSFER PHOTOOXYGENATION OF AZIRIDINES
Schaap, A. Paul,Prasad, Girija,Siddiqui, Shahabuddin
, p. 3035 - 3038 (2007/10/02)
DCA-sensitized photooxygenation of cis- and trans-2,3-diphenylaziridine in acetonitrile yields exclusively cis-3,5-diphenyl-1,2,4-dioxazolidine.Photooxygenation of N-alkyl-substituted 2,3-diphenylaziridines provides both isomers of the peroxide.The cis/tr
