Tetrahedron Letters p. 3047 - 3050 (1983)
Update date:2022-08-03
Topics: Radical Substrate Photooxygenation Oxygenation Heterocyclic Electron-transfer
Schaap, A. Paul
Prasad, Girija
Gagnon, Steven D.
Electron-transfer photooxygenation of 1-butyl-2,3-diphenylaziridine with 9,10-dicyanoanthracene in oxygen-saturated acetonitrile yields 4-butyl-3,5-diphenyl-1,2,4-dioxazolidine.This peroxide is surprisingly stable in nonpolar solvents decomposing to benzaldehyde and N-butylbenzamide upon heating to 100 deg C in benzene.Treatment with triphenyl phosphine yields benzaldehyde and N-butyl-1-phenylmethanimine.
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Doi:10.1016/S0031-9422(00)80288-5
(1983)Doi:10.1039/b512442e
(2006)Doi:10.1246/cl.1983.1267
(1983)Doi:10.1021/ol052943c
(2006)Doi:10.1007/BF00516461
(1983)Doi:10.1039/b516017k
(2006)
