87968-36-3Relevant academic research and scientific papers
Pd(II)-Catalyzed CC Bond Cleavage by a Formal Group-Exchange Reaction
Ye, Runyou,Zhu, Maoshuai,Yan, Xufei,Long, Yang,Xia, Ying,Zhou, Xiangge
, p. 8678 - 8683 (2021/07/26)
A chelation-assisted palladium-catalyzed CC bond cleavage of α, β-unsaturated ketone to form alkenyl nitrile in the presence of nitrile is disclosed on the basis of a formal group-exchange reaction formulated as C1C2 + C3 → C1C3 + C2, differing from normal alkene oxidative cleavage and metathesis type. The isolated key active Pd(II) complex as well as deuterium-labeled experiment revealed the necessity of the chelation group, and a plausible catalytic pathway was proposed.
THE PHOTOCHEMISTRY OF α-SUBSTITUTED 2-VINYLSTILBENS
Brouw, Paul M. op den,Laarhoven, Wim H.
, p. 1015 - 1020 (2007/10/02)
Irradiation of a solution of 2-vinylstilbene (1) under anaerobic conditions gives 9-phenyltricyclo2.7>deca-2,4,6-triene.Derivatives of (1), substituted at the α-position of the stilbene double bond, give 2-substituted 3-phenyltricyclo4
