879874-31-4Relevant academic research and scientific papers
Enantioselective CuII-catalyzed Diels-Alder and Michael addition reactions in water using bio-inspired triazacyclophane-based ligands
Bauke Albada,Rosati, Fiora,Coquiere, David,Roelfes, Gerard,Liskamp, Rob M. J.
scheme or table, p. 1714 - 1720 (2011/05/04)
A triazacyclophane (TAC) scaffold decorated with three histidine amino acid residues was used as a tridentate ligand in asymmetric copper(II)-catalysed Diels-Alder and Michael addition reactions in water. Enantiomeric excesses up to 55 % were obtained in
