87994-94-3Relevant academic research and scientific papers
6-Methylenebicyclo[3.2.1]oct-1-en-3-one: A Twisted Olefin as Diels–Alder Dienophile for Expedited Syntheses of Four Kaurane Diterpenoids
Wang, Junjie,Ma, Dawei
, p. 15731 - 15735 (2019)
6-Methylenebicyclo[3.2.1]oct-1-en-3-one, a twisted and highly reactive enone, was prepared for the first time by elimination of its bromide precursor. Its reactions as a dienophile with several dienes in Diels–Alder reactions proceeded smoothly to provide
Determining a synthetic approach to pierisformaside C
Chow, Sharon,Kress, Christoph,Albaek, Nanna,Jessen, Carsten,Williams, Craig M.
supporting information; experimental part, p. 5286 - 5289 (2011/12/14)
An efficient route detailing the construction of the central core of pierisformaside C, the first grayanane-type diterpene to possess three central double bonds, is reported.
THE SYNTHESIS OF FUSED AND BRIDGED RING SYSTEMS BY FREE RADICAL CARBOCYCLIZATION. A GENERAL ROUTE TO MASKED 1,4-DIKETONES.
Marinovic, N. N.,Ramanathan, H.
, p. 1871 - 1874 (2007/10/02)
A new method for the synthesis of fused and bridged ring systems based on intramolecular addition of a vinyl radical to α,β-unsaturated carbonyls is described.The method represents a general route to masked γ-diketones.
