87995-07-1Relevant academic research and scientific papers
Organosilicon radical-induced cyclization reactions
Kraus, George A.,Liras, Spiros
, p. 5265 - 5268 (2007/10/02)
The first examples of selective additions of organosilicon radicals are reported. Trichlorosilyl radicals preferentially attack the carbonyl oxygen atom, while triethylsilyl radicals preferentially attack alkenes. Carbon-carbon bond formation to produce b
THE SYNTHESIS OF FUSED AND BRIDGED RING SYSTEMS BY FREE RADICAL CARBOCYCLIZATION. A GENERAL ROUTE TO MASKED 1,4-DIKETONES.
Marinovic, N. N.,Ramanathan, H.
, p. 1871 - 1874 (2007/10/02)
A new method for the synthesis of fused and bridged ring systems based on intramolecular addition of a vinyl radical to α,β-unsaturated carbonyls is described.The method represents a general route to masked γ-diketones.
