88001-75-6Relevant academic research and scientific papers
Dehydrohalogenation of adducts of dichloro(pentafluorophenyl)borane with mesidine and p-anisidine: A reinvestigation
Morse, Joseph G.,Kent Glanville
, p. 11 - 13 (2008/10/08)
The pyrolysis of dichloro(pentafluorophenyl)borane with mesidine or p-anisidine, originally reported to yield monomeric boron imides, has been restudied. Rather than boron imides, the reactions give aminoboranes, (aminoboranyl)aminoboranes, or bis(amino)boranes depending on the duration of pyrolysis. The dimer structure represents an intermediate proposed in the pyrolysis of dichlorophenylborane with aromatic amines to give diazadiboranaphthalenes. Chemical dehydrohalogenation with 1,8-bis(dimethylamino)naphthalene leads directly to the bis(amino)boranes.
