19938-95-5Relevant academic research and scientific papers
Acid-Mediated Oxychalcogenation of o-Vinylanilides with N-(Arylthio/arylseleno)succinimides
Chaitanya, Manthena,Anbarasan, Pazhamalai
, p. 1183 - 1186 (2018)
An efficient acid-mediated oxythiolation of o-vinylanilides has been accomplished, employing N-(arylthio)succinimide as an electrophilic arylthiolating reagent for the synthesis of various arylthio tethered benzoxazine derivatives in good to excellent yie
Palladium(ii)-catalyzed vinylic geminal double C-H activation and alkyne annulation reaction: Synthesis of pentafulvenes
Phukon, Jyotshna,Gogoi, Sanjib
, p. 1133 - 1136 (2020/02/04)
The first transition-metal-catalyzed vinylic geminal double C(sp2)-H activation and di-substituted alkyne annulation reaction is reported. This palladium(ii)-catalyzed, amide directed reaction of vinylic compounds with di-substituted alkynes offers an efficient synthetic path to pentafulvenes, which are very important compounds because of their bioactivity and interesting optical properties. A FeCl3-mediated transformation of pentafulvenes to fluorescent cyclopenta[b]quinolines is also developed.
