88008-67-7Relevant articles and documents
GEZIELTE SYNTHESE DREIKERNIGER HETEROMETALL-CLUSTER MIT VIER VERSCHIEDENEN GERUESTATOMEN
Thometzek, P.,Werner, H.
, p. C29 - C34 (1983)
The trinuclear heterometallic cluster Va-Vc possessing a tetrahedral framework of four different atoms (MPdPtC) have been prepared from (μ-2-MeC3H4)(μ-Br)PdPt(PPr3i)2 (IV) and Na (M = Cr, M, W).Complex IV is obtained from (μ-2-MeC3H4)(μ-C5H5)PdPt(PPr3i)2 and Me3SiBr by bridge-ligand exchange.Following the same concept, the synthesis of the Pt2Mo and Pt2W heterometallic clusters VIIIa, VIIIb has also been achieved.