GEZIELTE SYNTHESE DREIKERNIGER HETEROMETALL-CLUSTER MIT VIER VERSCHIEDENEN GERUESTATOMEN

DOI: 10.1016/0022-328X(83)80093-X

Source and publish data:

Journal of Organometallic Chemistry p. C29 - C34 (1983)

Update date:2022-08-03

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Authors:

Thometzek, P.

Werner, H.

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Article abstract of DOI:10.1016/0022-328X(83)80093-X

The trinuclear heterometallic cluster Va-Vc possessing a tetrahedral framework of four different atoms (MPdPtC) have been prepared from (μ-2-MeC3H4)(μ-Br)PdPt(PPr3ⁱ)2 (IV) and Na (M = Cr, M, W).Complex IV is obtained from (μ-2-MeC3H4)(μ-C5H5)PdPt(PPr3ⁱ)2 and Me3SiBr by bridge-ligand exchange.Following the same concept, the synthesis of the Pt2Mo and Pt2W heterometallic clusters VIIIa, VIIIb has also been achieved.

Full text of DOI:10.1016/0022-328X(83)80093-X

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