88011-88-5Relevant articles and documents
On the mechanism of deoxygenation of secondary alcohols by tin hydride reduction of methyl xanthates and other thiocarbonyl derivatives
Barton,Jang,Jaszberenyi Cs.
, p. 3991 - 3994 (2007/10/02)
The room temperature deoxygenation of xanthates and thionocarbonates using (n - Bu) 3Sn-H - Et3B - air has been studied, especially with 119Sn N.M.R. spectroscopy. The orignal conception of tin radical attack on thiocarbonyl is confirmed.