88029-33-8Relevant academic research and scientific papers
Iridium(V) and Rhodium(V) Intermediates in Aromatic Metallation; the Unusual Reactivity of Iodobenzene
Gomez, Manuel,Robinson, David J.,Maitlis, Peter M.
, p. 825 - 826 (1983)
reacts with arenes (C6H5X) to give methane and a mixture of m- and p-substituted ; the order of reactivity is X = I > NO2 > CF3 > Br > H > OMe > Cl > F > Me; iridium(V) species are proposed as intermediates.
