Iridium(V) and Rhodium(V) Intermediates in Aromatic Metallation; the Unusual Reactivity of Iodobenzene

DOI: 10.1039/c39830000825

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 825 - 826 (1983)

Update date:2022-08-05

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Authors:

Gomez, Manuel

Robinson, David J.

Maitlis, Peter M.

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Article abstract of DOI:10.1039/c39830000825

<(C5Me5)Ir(Me)2(Me2SO)> reacts with arenes (C6H5X) to give methane and a mixture of m- and p-substituted <(C5Me5)Ir(Me)(C6H4X)(Me2SO)>; the order of reactivity is X = I > NO2 > CF3 > Br > H > OMe > Cl > F > Me; iridium(V) species are proposed as intermediates.

Full text of DOI:10.1039/c39830000825

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