
Journal of the Chemical Society. Chemical communications p. 825 - 826 (1983)
Update date:2022-08-05
Topics:
Gomez, Manuel
Robinson, David J.
Maitlis, Peter M.
<(C5Me5)Ir(Me)2(Me2SO)> reacts with arenes (C6H5X) to give methane and a mixture of m- and p-substituted <(C5Me5)Ir(Me)(C6H4X)(Me2SO)>; the order of reactivity is X = I > NO2 > CF3 > Br > H > OMe > Cl > F > Me; iridium(V) species are proposed as intermediates.
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