88034-54-2Relevant academic research and scientific papers
Structural characterisation of the first mononuclear bismuth porphyrin
Boitrel, Bernard,Halime, Zakaria,Michaudet, Lydie,Lachkar, Mohamed,Toupet, Loic
, p. 2670 - 2671 (2003)
A single carboxylate picket bismuth porphyrin has been characterised in the solid state as the first instance of a non-dimeric structure; the carboxylate picket, bent over the macrocycle, is coordinated to the bismuth, inducing a significant distortion of
Porphyrin synthesis in surfactant solution: Multicomponent assembly in micelles
Bonar-Law, Richard P.
, p. 3623 - 3634 (2007/10/03)
A synthesis of meso-substituted porphyrins in anionic sodium dodecyl sulfate micelles has been developed. Polar, functionalized aromatic aldehydes condense reversibly with pyrrole in the micellar phase. Oxidation of the porphyrinogen then provides functionalized porphyrins in yields of 10-48%. Hydrophobic aldehydes condense irreversibly to give low yields at practical substrate concentrations. Synthesis in D2O solution results in per-β-deuterated porphyrins. A two-phase model is used to rationalize the dependence of porphyrin yield on reactant and surfactant concentration. Micelles are viewed as potential wells which promote porphyrinogen assembly by binding products more tightly than reactants.
PORPHYRINS AND THEIR DERIVATIVES. I. SYNTHESIS AND CHARACTERISTICS OF STERICALLY SCREENED PORPHYRINS
Bogat-skii, A. V.,Zhilina, Z. I.,Krasnoshchekaya, S. P.,Zakharova, R. M.
, p. 2035 - 2039 (2007/10/02)
meso-Tetra(o-nitrophenyl)porphyrin was obtained by the acid condensation of o-nitrobenzaldehyde and pyrrole, and its reduction with stannous chloride led to meso-tetra(o-aminophenyl)porphyrin.The α,α,α,α-isomer of meso-tetra(o-aminophenyl)porphyrin was is
