88047-73-8Relevant academic research and scientific papers
Synthesis of ω-aminodithioesters
Lacroix, Simon,Rixhon, Vinciane,Marchand-Brynaert, Jacqueline
, p. 2327 - 2334 (2008/02/03)
ω-Aminodithioester derivatives were obtained from thionolactams by reaction with an alkyl triflate followed by thiolysis with hydrogen sulfide. The presence of an electron-withdrawing group was required on the N1 position (p-nitrophenyl or benzoyl) to favor the ring opening of γ-, δ- and ε-thionolactams. In the case of β-thionolactam, activation was provided by a CF2 motif in C3 position. Georg Thieme Verlag Stuttgart.
A Convenient Synthesis of Azetidine-2-thiones and Azetidin-2-imines
Marchand-Brynaert, Jacqueline,Moya-Portuguez, Manuel,Huber, Isabelle,Ghosez, Leon
, p. 818 - 819 (2007/10/02)
Azetidin-2-iminium salts, which are readily available from tertiary amides, can be easily converted into the corresponding thiones or imines.
