88054-75-5

Upstream product

• 88054-72-2 5-O-(imidazol-1-yl-thiocarbonyl)-1,2-O-isopropylidene-5-C-(methoxyphenylphosphinyl)-3-O-methyl-α-D-xylofuranose 
• 88054-71-1 1,2-isopropylidene-5-C-(methoxyphenylphosphinyl)-3-O-methyl-α-D-xylofuranose 
• 18968-51-9 1,2-O-isopropylidene-3-O-methyl-α-D-xylo-pentodialdo-1,4-furanose 
• 7162-15-4 methyl phenylphosphinate 
• 88054-73-3 5-deoxy-1,2-O-isopropylidene-5-C-(methoxyphenylphosphinyl)-3-O-methyl-α-D-xylofuranose 
• 30694-42-9 5-deoxy-5-C-<(ethoxy)phenylphosphinyl>-1,2-O-isopropylidene-3-O-methyl-α-D-xylofuranose 

Downstream Products

• 88054-83-5 1,2,4-tri-O-acetyl-5-deoxy-3-O-methyl-5-C-<(R)-phenylphosphinyl>-α-D-xylopyranose 
• 88054-82-4 1,2,4-tri-O-acetyl-5-deoxy-3-O-methyl-5-C-<(R)-phenylphosphinyl>-β-D-xylopyranose 
• 88054-80-2 1,2,4-tri-O-acetyl-5-deoxy-3-O-methyl-5-C-<(S)-phenylphosphinyl>-α-D-xylopyranose 
• 88054-81-3 1,2,4-tri-O-acetyl-5-deoxy-3-O-methyl-5-C-<(S)-phenylphosphinyl>-β-D-xylopyranose 

Relevant academic research and scientific papers

Synthesis and Structural Analysis of 5-Deoxy-3-O-methyl-5-C--α- and β-D-xylopyranoses

Treatment of 5-deoxy-5-iodo-1,2-O-isopropylidene-3-O-methyl-α-D-xylofuranose with ethyl phenylphosphinothioate in the presence of NaH in DMF gave a 1:1 mixture of the 5-deoxy-5-C- derivatives.Reduction of these

A NEW ROUTE FOR FORMATION OF THE CARBON-PHOSPHORUS BOND, AND SYNTHESIS OF 1,2,4-TRI-O-ACETYL-5-DEOXY-3-O-METHYL-5-C--α- AND -β-D-XYLOPYRANOSE

Deoxygenation at the carbon atom α to the phosphorus atom of 1,2-O-isopropylidene-5-C-(methoxyphenylphosphinyl)-3-O-methyl-α-D-xylofuranose (7), prepared from 1,2-isopropylidene-3-O-methyl-α-D-xylo-pentodialdo-1,4-furanose by reaction with methyl phenylph