88054-82-4Relevant articles and documents
A NEW ROUTE FOR FORMATION OF THE CARBON-PHOSPHORUS BOND, AND SYNTHESIS OF 1,2,4-TRI-O-ACETYL-5-DEOXY-3-O-METHYL-5-C--α- AND -β-D-XYLOPYRANOSE
Seo, Kuniaki
, p. 101 - 108 (1983)
Deoxygenation at the carbon atom α to the phosphorus atom of 1,2-O-isopropylidene-5-C-(methoxyphenylphosphinyl)-3-O-methyl-α-D-xylofuranose (7), prepared from 1,2-isopropylidene-3-O-methyl-α-D-xylo-pentodialdo-1,4-furanose by reaction with methyl phenylph
Synthesis of 1,2,4-Tri-O-acetyl-5-deoxy-5-3-O-methyl-α,β-D-xylopyranoses and an Efficient Conversion to the Corresponding 5-(Phosphinothioyl)-D-xylopyranoses
Yamamoto, Hiroshi,Hanaya, Tadashi,Shigetoh, Nobuyuki,Kawamoto, Heizan,Inokawa, Saburo
, p. 349 - 352 (2007/10/02)
Reduction of 1,2,4-tri-O-acetyl-5-deoxy-5--α,β-D-xylopyranoses with trichlorosilane in benzene in the presence of triethylamine smoothly afforded the corresponding title 5-phosphino-D-xylopyranoses (10-13a,b) without cau
Synthesis and Structural Analysis of 5-Deoxy-3-O-methyl-5-C--α- and β-D-xylopyranoses
Hanaya, Tadashi,Shigetoh, Nobuyuki,Yamamoto, Hiroshi
, p. 2499 - 2506 (2007/10/02)
Treatment of 5-deoxy-5-iodo-1,2-O-isopropylidene-3-O-methyl-α-D-xylofuranose with ethyl phenylphosphinothioate in the presence of NaH in DMF gave a 1:1 mixture of the 5-deoxy-5-C- derivatives.Reduction of these