880644-70-2Relevant academic research and scientific papers
A new family of biisoquinoline chelates
Durola, Fabien,Hanss, David,Roesel, Pirmin,Sauvage, Jean-Pierre,Wenger, Oliver S.
, p. 125 - 135 (2007/10/03)
Four 8,8′-diaryl-substituted 3,3′-biisoquinoline ligands have been synthesized and characterized. The key feature of this new family of chelates is their endotopic but sterically non-hindering nature. All four ligands were made from a common 8-bromoisoquinolin-3-ol precursor; between three and twelve synthetic steps were necessary to obtain the products. The reported synthetic procedures allow for gram-scale production of these biisoquinolines. Wiley-VCH Verlag GmbH & Co. KGaA, 2007.
Sterically non-hindering endocyclic ligands of the bi-isoquinoline family
Durola, Fabien,Sauvage, Jean-Pierre,Wenger, Oliver S.
, p. 171 - 173 (2008/02/08)
Bi-isoquinoline can be used as a building block to prepare a new family of non-sterically hindering chelates, including a macrocyclic system; the endocyclic nature of the ligands has been confirmed by the X-ray structure of an octahedral tris-chelate iron
