88068-36-4Relevant academic research and scientific papers
Manganese-Promoted Oxidative Cyclization of Unsaturated Oximes Using Molecular Oxygen in Air under Ambient Conditions
Yamamoto, Daisuke,Oguro, Takuto,Tashiro, Yuuki,Soga, Masayuki,Miyashita, Kazuhito,Aso, Yoshiaki,Makino, Kazuishi
, p. 5216 - 5219 (2016/11/13)
A highly efficient manganese-promoted oxidative cyclization of unsaturated oximes to afford the corresponding 4,5-dihydroisoxazoline alcohols was developed. A very low loading (generally 0.1–0.2 mol-%) of Mn(acac)3(acac = acetylacetonate) promoted the oxidative cyclization through the direct incorporation of molecular oxygen present in air (open flask) at room temperature.
THE ALKYLATION AND BASE-PROMOTED RING-OPENING REACTION OF 3-PHENYLSULFONYL-3-TRIMETHYLSILYLCYCLOBUTANOLS. A NEW METHOD FOR THE PREPARATION OF β-METHYLENE KETONES
Takeda, Takeshi,Ando, Kazuo,Fujiwara, Tooru
, p. 1285 - 1288 (2007/10/02)
β-Methylene ketones were produced by the alkylation of 1-alkyl-3-phenylsulfonyl-3-trimethylsilylcyclobutanols followed by the treatment with potassium hydride.
