88073-46-5Relevant academic research and scientific papers
Elimination and Addition Reactions. Part 40. The Insignificant Effect of Strain in Higher Order Eliminations in 1,1-bis(phenylsulphonyl) Carbanions with ω-Leaving Groups
Benedetti, Fabio,Stirling, Charles J.M.
, p. 605 - 612 (2007/10/02)
Rates of cyclisation of 1,1-bis(phenylsulphonyl) carbanions bearing distal leaving groups have been determined.The response of the system to solvent effects and to leaving group is similar to that in intramolecular nucleophilic substitution.The system is
Hydrogen Bonds involving Polar CH Groups. Part 10. Intramolecular Hydrogen Bonds in 1-(ω-Substituted-alkyl) Bis(phenylsulphonyl)methanes
Li, Chuen,Sammes, Michael P.
, p. 2193 - 2196 (2007/10/02)
Intramolecular hydrogen bonds involving the polar methine group have been detected by 1H n.m.r. spectroscopy in dichloromethane in 1-(ω-methoxyalkyl)- and 1-(ω-dialkylaminoalkyl)-bis(phenylsulphonyl)methanes.Dialkylamino groups are more effective don
