88073-51-2Relevant articles and documents
Aryl(sulfonyl)amino group: A convenient and stable yet activated modification of amino group for its intramolecular displacement
Kato, Yuzo,Yen, Dinh Hoang,Fukudome, Yasuhiro,Hata, Takeshi,Urabe, Hirokazu
supporting information; experimental part, p. 4137 - 4139 (2010/11/04)
Aryl(sulfonyl)amino groups, readily derived from sulfonyl- or arylamines by standard methods as well as the recently introduced methods of sulfonylation and arylation, proved to be good leaving groups in intramolecular substitution reactions by various nitrogen, oxygen, and carbon nucleophiles.
Elimination and Addition Reactions. Part 40. The Insignificant Effect of Strain in Higher Order Eliminations in 1,1-bis(phenylsulphonyl) Carbanions with ω-Leaving Groups
Benedetti, Fabio,Stirling, Charles J.M.
, p. 605 - 612 (2007/10/02)
Rates of cyclisation of 1,1-bis(phenylsulphonyl) carbanions bearing distal leaving groups have been determined.The response of the system to solvent effects and to leaving group is similar to that in intramolecular nucleophilic substitution.The system is
Activation Parameters for Intramolecular Nucleophilic Substitution by Carbanions - the Insignificant Effect of Ring Strain on Cylisation Rates
Benedetti, Fabio,Stirling, Charles J. M.
, p. 1374 - 1376 (2007/10/02)
Activation parameters for the cyclisation of bis-sulphonyl-stabilised carbanions to bis-sulphonylcycloalkanes have been determined; cyclopropanes form nearly a million-fold faster than cyclobutanes and ring strain is a negligible factor in determining rea