88082-90-0

Upstream product

• 925211-06-9 bicyclo(3.2.0)hept-2-en-6-one 

Downstream Products

• 135092-51-2 (S)-2-(4-Chloro-phenoxy)-propionic acid (1S,5R,6S)-bicyclo[3.2.0]hept-2-en-6-yl ester 
• 135092-52-3 (R)-2-(4-Chloro-phenoxy)-propionic acid (1S,5R,6S)-bicyclo[3.2.0]hept-2-en-6-yl ester 
• 134919-53-2 (S)-2-(4-Chloro-phenoxy)-propionic acid (1R,5S,6R)-bicyclo[3.2.0]hept-2-en-6-yl ester 
• 135092-50-1 (R)-2-(4-Chloro-phenoxy)-propionic acid (1R,5S,6R)-bicyclo[3.2.0]hept-2-en-6-yl ester 
• 34638-25-0 (1R,5S)-2-oxabicyclo[3.3.0]oct-6-en-3-one 
• 26054-46-6 (-)-(1S,5R)-2-oxabicyclo[3.3.0]oct-6-en-3-one 
• 103618-27-5 (+)-(1S,5R)-3-oxabicyclo<3.3.0>oct-6-en-2-one 
• 13173-09-6 bicyclo[3.2.0]hept-2-en-6-one 
• 1521-45-5 endo-bicyclo[3.2.0]hept-2-en-6-ol acetate 
• 1623755-30-5 methyl-3-((1S,2R,3S)-2-(2-((4-methoxyphenyl)diphenylmethoxy)ethyl)-3-((triisopropylsilyl)oxy)cyclobutyl)-3-oxopropanoate 
• 1623755-28-1 (1S,2R,3S)-2-(2-((4-methoxyphenyl)diphenylmethoxy)ethyl)-3-((triisopropylsilyl)oxy)cyclobutanecarbaldehyde 
• 1623755-76-9 (1R,2R,3S)-2-(2-((4-methoxyphenyl)diphenylmethoxy)ethyl)-3-((triisopropylsilyl)oxy)cyclobutanecarbaldehyde 
• 1623755-25-8 ((1R,2R,3S)-2-(2-((4-methoxyphenyl)diphenylmethoxy)ethyl)-3-((triisopropylsilyl)oxy)cyclobutyl)methanol 
• 1623755-73-6 2-((1R,2R,4S)-2-(((4-methoxyphenyl)diphenylmethoxy)methyl)-4-((triisopropylsilyl)oxy)cyclobutyl)ethanol 

Relevant academic research and scientific papers

A one-pot remote allylic hydroxylation and Baeyer-Villiger oxidation of a bicyclo[3.2.0]hept-2-en-6-one by Cunninghamella echinulata NRRL 3655.

7-exo-Methyl-7-endo-phenylbicyclo[3.2.0]hept-2-en-6-one 3 undergoes Baeyer-Villiger and allylic oxidation, to yield novel hydroxylactone 8 in good yield by Cunninghamella echinulata NRRL 3655, representing a one step biocatalytic access to a cyclopentanoid scaffold with three chiral centers. Interesting, allylic oxidation occurs with transposition of the double bond.