880876-74-4

Upstream product

• 2186-92-7 p-Anisaldehyde dimethyl acetal 
• 862465-84-7 tert-butyl 2-((6S,4R)-6-{[1,1-bis(1-methylethyl)-2-methyl-1-silapropoxy]methyl}-2-(4-methoxyphenyl)-1,3-dioxan-4-yl)acetate 
• 625124-76-7 tert-butyl 2-[(6S,4R)-6-(hydroxymethyl)-2-(4-methoxyphenyl)-1,3-dioxan-4-yl]acetate 
• 153716-95-1 (3R,5S)-6-benzyloxy-3,5-dihydroxy-hexanoic acid tert-butyl ester 
• 101712-01-0 (R)-1-((R)-4-benzyl-2-oxooxazolidin-3-yl)-2-methylpentane-1,3-dione 
• 862465-74-5 (R)-4-Benzyl-3-[(E)-(2R,3S,4R,5R,6R,7R)-3-hydroxy-7-(4-methoxy-benzyloxy)-2,4,6-trimethyl-9-phenyl-5-triethylsilanyloxy-non-8-enoyl]-oxazolidin-2-one 
• 862465-86-9 (4S)-3-[4-(6-{(2S)-3-[1,1-bis(1-methylethyl)-2-methyl-1-silapropoxy]-2-[(4-methoxyphenyl)methoxy]propyl}(4S,6R)-2,2-dimethyl(1,3-dioxan-4-yl))(2S,3R)-3-hydroxy-2-methylbutanoyl]-4-benzyl-1,3-oxazolidin-2-one 
• 862465-90-5 1-(4'R-benzyl-2'-oxo-oxazolidin-3'-yl)-7R-(4-methoxy-benzyloxy)-2R,4S,6R-trimethyl-9-phenyl-5S-(triethyl-silanyloxy)-non-8-ene-1,3-dione 
• 862465-87-0 4-((4R,6R)-6-{(2S)-3-[1,1-bis(1-methylethyl)-2-methyl-1-silapropoxy]-2-[(4-methoxyphenyl)methoxy]propyl}-2,2-dimethyl(1,3-dioxan-4-yl))(2S,3R)-N-methoxy-2-methyl-N-methyl-3-(tert-butyldimethylsilyloxy)butanamide 
• 862465-75-6 4R-benzyl-3-(2'R-{6''S-[2'''R-(4-methoxy-benzyloxy)-1'''R-methyl-4'''-phenyl-but-3'''-enyl]-2'',2'',5''S-trimethyl-[1,3]dioxan-4''S-yl}-propionyl)-oxazolidin-2-one 
• 862465-61-0 6-(6-{(3E)(1R,2R)-2-[(4-methoxyphenyl)methoxy]-1-methyl-4-phenylbut-3-enyl}(4S,4S,6S)-2,2,5-trimethyl(1,3-dioxan-4-yl))(5R,6R)-5-(tert-butyldimethylsilyloxy)heptan-3-one 
• 862465-73-4 1-(4'R-benzyl-2'-oxo-oxazolidin-3'-yl)-5S-hydroxy-7R-(4-methoxy-benzyloxy)-2R,4S,6R-trimethyl-9-phenyl-non-8-ene-1,3-dione 
• 862465-62-1 4-((4R,6R)-6-{(2S)-3-[1,1-bis(1-methylethyl)-2-methyl-1-silapropoxy]-2-[(4-methoxyphenyl)methoxy]propyl}-2,2-dimethyl(1,3-dioxan-4-yl))(2S,3R)-2-methyl-3-(tert-butyldimethylsilyloxy)butan-1-one 
• 862465-69-8 4-(6-{(2S)-3-[1,1-bis(1-methylethyl)-2-methyl-1-silapropoxy]-2-[(4-methoxyphenyl)methoxy]propyl}(4S,6R)-2,2-dimethyl(1,3-dioxan-4-yl))(2S,3R)-3-hydroxy-N-methoxy-2-methyl-N-methylbutanamide 

Downstream Products

• 862465-81-4 C₇₉H₁₃₄O₁₃Si₃ 

Relevant academic research and scientific papers

Synthesis and confirmation of the absolute stereochemistry of the (-)-af lastatin A C9-C27 degradation polyol

(Chemical Equation Presented) The C8-C18 ethyl ketone and C19-C28 aldehyde aflastatin A fragments were synthesized and coupled using a diastereoselective anti aldol reaction. This adduct was successfully convert