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88088-52-2

(3R,4S)-4-Methyl-1-phenyl-hex-5-en-1-yn-3-ol is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 88088-52-2 Structure

  • Basic information

    1. Product Name: (3R,4S)-4-Methyl-1-phenyl-hex-5-en-1-yn-3-ol
    2. Synonyms:
    3. CAS NO:88088-52-2
    4. Molecular Formula:
    5. Molecular Weight: 186.254
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 88088-52-2.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: (3R,4S)-4-Methyl-1-phenyl-hex-5-en-1-yn-3-ol(CAS DataBase Reference)
    10. NIST Chemistry Reference: (3R,4S)-4-Methyl-1-phenyl-hex-5-en-1-yn-3-ol(88088-52-2)
    11. EPA Substance Registry System: (3R,4S)-4-Methyl-1-phenyl-hex-5-en-1-yn-3-ol(88088-52-2)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 88088-52-2(Hazardous Substances Data)

88088-52-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 88088-52-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,8,0,8 and 8 respectively; the second part has 2 digits, 5 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 88088-52:
(7*8)+(6*8)+(5*0)+(4*8)+(3*8)+(2*5)+(1*2)=172
172 % 10 = 2
So 88088-52-2 is a valid CAS Registry Number.

88088-52-2Relevant articles and documents

-WITTIG SIGMATROPIC REARRANGEMENT OF CROTYL PROPARGYL ETHER SYSTEM; AN EMERGING TOOL FOR CONTROL OF ACYCLIC STEREOCHEMISTRY

Mikami, Koichi,Azuma, Ken-Ichi,Nakai, Takeshi

, p. 2303 - 2308 (2007/10/02)

The -Wittig rearrangement of properly designated (E)- and (Z)-crotyl propargyl ether system has been shown to exhibit a remarkably high degree of threo- and erythro-selection, respectively, and the stereochemical outcomes are discussed on mechanistic grounds.Some useful transformations of the rearrangement product are also described within the context of the formal total synthesis of (+/-)-oudemansin.Further, the high level of diastereoselection is maintained in the reaction of the α-methylcrotyl counterparts, together with the exclusive formation of the (E)-olefinic bond.

ENHANCEMENT OF ERYTHRO-SELECTIVITY IN THE -WITTIG REARRANGEMENT OF CROTYL PROPARGYL ETHER SYSTEM AND ITS USE IN THE STEREOCONTROLLED FORMAL SYNTHESIS OF (+/-)-OUDEMANSIN

Mikami, Koichi,Azuma, Ken-ichi,Nakai, Takeshi

, p. 1379 - 1382 (2007/10/02)

The -Wittig variant of (Z)-crotyl ether involving trimethylsilylethynyl (or 1-propynyl) group as the key substituent on the carbanion terminus exhibits an exceptionally high level of erythro-selection, and its synthetic potential is illustrated in th

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