88088-55-5

Basic information

• Product Name: (E)-4-Methoxy-3-methyl-6-phenyl-hex-5-en-1-ol
• CAS NO: 88088-55-5
• Molecular Weight: 220.312
• Mol File: 88088-55-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (E)-4-Methoxy-3-methyl-6-phenyl-hex-5-en-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-4-Methoxy-3-methyl-6-phenyl-hex-5-en-1-ol(88088-55-5)
• EPA Substance Registry System: (E)-4-Methoxy-3-methyl-6-phenyl-hex-5-en-1-ol(88088-55-5)

Safety Data

• Hazardous Substances Data: 88088-55-5(Hazardous Substances Data)

Upstream product

• 79705-05-8 (E)-1-(prop-2-yn-1-yloxy)but-2-ene 
• 79705-07-0 (3S,4R)-4-Methyl-hex-5-en-1-yn-3-ol 
• 88088-52-2 (3R,4S)-4-Methyl-1-phenyl-hex-5-en-1-yn-3-ol 
• 87763-64-2 (2S,3R)-2-Methoxy-3-methyl-pent-4-enoic acid methyl ester 
• 106315-57-5 (3R,4S)-1-(Diphenyl-phosphinoyl)-3-methoxy-4-methyl-1-phenyl-hex-5-en-2-one 
• 591-50-4 iodobenzene 
• 106315-57-5 1-(Diphenyl-phosphinoyl)-3-methoxy-4-methyl-1-phenyl-hex-5-en-2-one 
• 344325-46-8 Methyl 2-Methoxy-3-methyl-4-pentenoate 
• 2959-74-2 benzyldiphenylphosphine oxide 
• 88088-48-6 (3S,4R)-4-Methyl-1-trimethylsilanyl-hex-5-en-1-yn-3-ol 
• 88088-42-0 {3-[((E)-But-2-enyl)oxy]-prop-1-ynyl}-trimethyl-silane 
• 84118-90-1 (syn)-(E)-3-hydroxy-4-methyl-1-phenyl-1,5-hexadiene 
• 88088-54-4 (E)-(3S^*,4R^*)-3-methoxy-4-methyl-1-phenylhexa-1,5-diene 

Downstream Products

• 88088-56-6 (E)-(3R,4S)-4-Methoxy-3-methyl-6-phenyl-hex-5-enoic acid 
• 88155-83-3 methyl (E)-(3R^*,4S^*)-4-methoxy-3-methyl-6-phenylhexa-5-enoate 
• 73341-71-6 (+/-)-oudemansin A 
• 73341-71-6 oudemansin A 
• 90664-08-7 (E)-(3S,4S)-2-Formyl-4-methoxy-3-methyl-6-phenyl-hex-5-enoic acid methyl ester 
• 109864-20-2 (E)-(3S,4S)-2-[1-Hydroxy-meth-(Z)-ylidene]-4-methoxy-3-methyl-6-phenyl-hex-5-enoic acid methyl ester 

Relevant articles and documents

Synthesis of the oudemansins, naturally occurring β-methoxyacrylates from basidomycetes

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-WITTIG SIGMATROPIC REARRANGEMENT OF CROTYL PROPARGYL ETHER SYSTEM; AN EMERGING TOOL FOR CONTROL OF ACYCLIC STEREOCHEMISTRY

The -Wittig rearrangement of properly designated (E)- and (Z)-crotyl propargyl ether system has been shown to exhibit a remarkably high degree of threo- and erythro-selection, respectively, and the stereochemical outcomes are discussed on mechanistic grounds.Some useful transformations of the rearrangement product are also described within the context of the formal total synthesis of (+/-)-oudemansin.Further, the high level of diastereoselection is maintained in the reaction of the α-methylcrotyl counterparts, together with the exclusive formation of the (E)-olefinic bond.