88088-57-7

Upstream product

• 6971-52-4 3-methoxy-2-methylphenol 
• 108-24-7 acetic anhydride 
• 88010-46-2 6-Bromo-3-methoxy-2-methyl-phenol 
• 105104-04-9 Acetic acid 6-bromo-4-formyl-3-methoxy-2-methyl-phenyl ester 

Downstream Products

• 88088-59-9 Acetic acid 4-((Z)-4-benzyloxy-but-2-enyloxy)-6-bromo-3-methoxy-2-methyl-phenyl ester 
• 109035-36-1 Acetic acid 4-allyloxy-6-bromo-3-methoxy-2-methyl-phenyl ester 
• 105104-08-3 2-Benzyloxy-1-bromo-4-methoxy-3-methyl-5-[((E)-penta-2,4-dienyl)oxy]-benzene 
• 105104-31-2 4-(benzyloxy)-3-bromo-6-methoxy-5-methyl-2-(2,4-pentadienyl)phenol 
• 105104-30-1 3-bromo-4-<(tert-butyldimethylsilyl)oxy>-6-dimethoxy-5-methyl-2-(2,4-pentadienyl)phenol 
• 105104-07-2 5-bromo-4-<(tert-butyldimethylsilyl)oxy>-2-methoxy-3-methylphenyl 2,4-pentadienyl ether 
• 105104-29-8 4-acetoxy-3-bromo-6-methoxy-5-methyl-2-(2,4-pentadienyl)phenol 
• 105104-06-1 6-bromo-3-methoxy-2-methyl-4-<(2,4-pentadienyl)oxy>phenyl 
• 88088-66-8 Methanesulfonic acid 4-benzyloxy-3-[2-bromo-3-(tert-butyl-dimethyl-silanyloxy)-5,6-dimethoxy-4-methyl-phenyl]-1-vinyl-butyl ester 
• 88088-65-7 6-Benzyloxy-5-[2-bromo-3-(tert-butyl-dimethyl-silanyloxy)-5,6-dimethoxy-4-methyl-phenyl]-hex-1-en-3-ol 
• 88088-67-9 [3-((E)-1-Benzyloxymethyl-penta-2,4-dienyl)-2-bromo-4,5-dimethoxy-6-methyl-phenoxy]-tert-butyl-dimethyl-silane 
• 88088-64-6 4-Benzyloxy-3-[2-bromo-3-(tert-butyl-dimethyl-silanyloxy)-5,6-dimethoxy-4-methyl-phenyl]-butyraldehyde 
• 88088-63-5 [3-(1-Benzyloxymethyl-allyl)-2-bromo-4,5-dimethoxy-6-methyl-phenoxy]-tert-butyl-dimethyl-silane 
• 88088-61-3 Acetic acid 3-(1-benzyloxymethyl-allyl)-2-bromo-4,5-dimethoxy-6-methyl-phenyl ester 

Relevant academic research and scientific papers

Lewis Acid Mediated Claisen-Type Rearrangement of Aryl Dienyl Ethers

Rearrangement of aryl pentadienyl ethers in the presence of BF3*OEt2 affords pentadienyl phenols in good yields without formation of the corresponding rearranged products.The mechanism of this rearrangement was studied by deuterium labeling and cross-coupling reactions.The scope and limitations of the rearrangement are discussed.

SYNTHETIC APPROACH TOWARD MITOMYCINS. SYNTHESIS OF 9-BENZYLOXYMETHYL-5-METHOXY-4-METHYL-3H-PYRROLOINDOL-4,5-DIONE

2-Azido-3-(1'-benzyloxymethyl-2',4'-pentadienyl)-5-methoxy-6-methyl-1,4-benzoquinone is prepared and its thermal decomposition under the presence of Cu(acac)2 affords the corresponding 3H-pyrroloindol-5,8-dione, which is the important precursor for