88090-53-3Relevant academic research and scientific papers
Molecules with Twist Bent Bonds. The Synthesis, Properties, and Reactions of trans-Bicyclohept-3-ene and Certain Methylated Derivatives
Gassman, Paul G.,Bonser, Steven M.,Mlinaric-Majerski, Kata
, p. 2652 - 2662 (2007/10/02)
trans-Bicyclohept-3-ene, 7-methyl-trans-bicyclohept-3-ene, and 7,7-dimethyl-trans-bicyclohept-3-ene have been synthesized.Comparison of their ease of oxidation with the ease of oxidation of the analogous cis-bicyclohept-3-enes has been made.Both the thermal and transition-metal complex promoted rearrangements of the trans-bicyclohept-3-enes have been studied.These systems thermally convert to the cis-bicyclohept-3-enes above 100 deg C and are catalytically rearranged at ambient temperature.Trans to cis isomerization alsooccurs at ambient temperature under photoinduced single electron transfer conditions.
THE TRANSITION METAL COMPLEX PROMOTED ISOMERIZATION OF trans-BICYCLOHEPT-3-ENE TO cis-BICYCLOHEPT-3-ENE
Gassman, Paul G.,Bonser, Steven M.
, p. 3431 - 3434 (2007/10/02)
An unprecedented isomerization of a trans-1,2-disubstituted cyclopropane to a cis-1,2-disubstituted cyclopropane has been achieved with both rhodium(I) and platinum(II) catalysts.
