72581-32-9

Basic information

• Product Name: 3-CYCLOHEXENE-1-METHANOL)
• CAS NO: 72581-32-9
• Molecular Formula: C₇H₁₂O
• Molecular Weight: 112.16958
• Mol File: 72581-32-9.mol
• Article Data: 96

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3-CYCLOHEXENE-1-METHANOL)(CAS DataBase Reference)
• NIST Chemistry Reference: 3-CYCLOHEXENE-1-METHANOL)(72581-32-9)
• EPA Substance Registry System: 3-CYCLOHEXENE-1-METHANOL)(72581-32-9)

Safety Data

• Hazardous Substances Data: 72581-32-9(Hazardous Substances Data)

Upstream product

• 100-50-5 3-Cyclohexene-1-carboxaldehyde 
• 50-00-0 formaldehyd 
• 110-83-8 cyclohexene 
• 1393559-72-2 (1,1-dioxo-2,3,6,7-tetrahydrothiepin-4-yl)methanol 
• 1393561-23-3 ethyl 2,3,6,7-tetrahydrothiepine-4-carboxylate 1,1-dioxide 
• 1393561-93-7 ethyl 2,3,6,7-tetrahydrothiepine-4-carboxylate 
• 1393561-91-5 C₁₀H₁₈O₅S₂ 
• 1393560-51-4 ethyl 5-hydroxythiepane-4-carboxylate 
• 925218-54-8 ethyl 5-oxothiepane-4-carboxylate 
• 1393560-00-3 (S)-(1,1-dioxothiepan-4-yl)methanol 
• 1072-72-6 Tetrahydrothiopyran-4-one 
• 72526-00-2 (-)-8-phenylmenthyl acrylate 
• 106-99-0 buta-1,3-diene 
• 87509-95-3 (S)-1-(S)-Cyclohex-3-enyl-2-hydroxy-3,3-dimethyl-butan-1-one 

Downstream Products

• 33324-13-9 (Cyclohex-3-enylmethoxy)-dimethyl-silane 
• 33324-15-1 1-cyclohex-3-enylmethoxy-1,1,3,3-tetramethyl-disiloxane 
• 5708-19-0 (1S)-3-cyclohexenecarboxylic acid 
• 10578-41-3 2-((cyclohex-3-en-1-ylmethoxy)methyl)oxirane 
• 99180-69-5 4-((allyloxy)methyl)cyclohex-1-ene 
• 290355-85-0 4-(tert-butyldimethylsilyloxymethyl)-cyclohex-1-ene 
• 141770-54-9 2-cyano-5-[3,6-dihydro-3,4-dimethyl-2,6-dioxo-1(2H)-pyrimidinyl]-4-fluorobenzoic acid 1,2,3,6-tetrahydrobenzyl ester 
• 93154-23-5 acetaldehyde di-(1,2,3,6-tetrahydrobenzyl)-acetal 
• 64630-63-3 1-acryloyloxymethyl-3,4-epoxycyclohexane 
• 81370-41-4 1-methylcarbonyloxymethyl-3-cyclohexene oxide 

Relevant articles and documents

Hydrogenation of Esters by Manganese Catalysts

The hydrogenation of esters catalyzed by a manganese complex of phosphine-aminopyridine ligand was developed. Using this protocol, a variety of (hetero)aromatic and aliphatic carboxylates including biomass-derived esters and lactones were hydrogenated to primary alcohols with 63–98% yields. The manganese catalyst was found to be active for the hydrogenation of methyl benzoate, providing benzyl alcohol with turnover numbers (TON) as high as 45,000. Investigation of catalyst intermediates indicated that the amido manganese complex was the active catalyst species for the reaction. (Figure presented.).

Ambient-pressure highly active hydrogenation of ketones and aldehydes catalyzed by a metal-ligand bifunctional iridium catalyst under base-free conditions in water

A green, efficient, and high active catalytic system for the hydrogenation of ketones and aldehydes to produce corresponding alcohols under atmospheric-pressure H2 gas and ambient temperature conditions was developed by a water-soluble metal–ligand bifunctional catalyst [Cp*Ir(2,2′-bpyO)(OH)][Na] in water without addition of a base. The catalyst exhibited high activity for the hydrogenation of ketones and aldehydes. Furthermore, it was worth noting that many readily reducible or labile functional groups in the same molecule, such as cyan, nitro, and ester groups, remained unchanged. Interestingly, the unsaturated aldehydes can be also selectively hydrogenated to give corresponding unsaturated alcohols with remaining C=C bond in good yields. In addition, this reaction could be extended to gram levels and has a large potential of wide application in future industrial.

Application of bis(phosphinite) pincer nickel complexes to the catalytic hydrosilylation of aldehydes

A series of bis(phosphinite) (POCOP) pincer ligated nickel complexes, [2,6-(tBu2PO)2C6H3]NiX (X = SH, 1; SCH2Ph, 2; SPh, 3; NCS, 4; N3, 5), were used to catalyse the hydrosilylation of aldehydes. It was found that both complexes 1 and 2 are active in catalysing the hydrosilylation of aldehydes with phenylsilane and complex 1 is comparatively more active. The expected alcohols were isolated in good to excellent yields after basic hydrolysis of the resultant hydrosilylation products. However, no reaction was observed when complex 3 or 4 or 5 was used as the catalyst. The results are consistent with complexes 1 and 2 serving as catalyst precursors, which generate the corresponding nickel hydride complex [2,6-(tBu2PO)2C6H3]NiH in situ, and the nickel hydride complex is the active species that catalyses this hydrosilylation process. The in situ generation of the nickel hydride species was supported by both experimental results and DFT calculation.