88095-33-4

Basic information

• Product Name: 3-(4,6-O-benzylidene-2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl)-1-propene
• Synonyms: 3-(4,6-O-benzylidene-2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl)-1-propene
• CAS NO: 88095-33-4
• Molecular Weight: 258.317
• Mol File: 88095-33-4.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 3-(4,6-O-benzylidene-2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl)-1-propene(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(4,6-O-benzylidene-2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl)-1-propene(88095-33-4)
• EPA Substance Registry System: 3-(4,6-O-benzylidene-2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl)-1-propene(88095-33-4)

Safety Data

• Hazardous Substances Data: 88095-33-4(Hazardous Substances Data)

Upstream product

• 14125-71-4 3-O-acetyl-4.6-O-benzylidene-D-arabino-hex-1-enitol 
• 762-72-1 allyl-trimethyl-silane 
• 82740-87-2 (2R,3S,6R)-2-acetoxymethyl-6-allyl-3,6-dihydro-2H-pyran-3-yl acetate 
• 2873-29-2 D-glucal triacetate 
• 2622-05-1 allylmagnesium bromide 
• 88095-31-2 1,5-anhydro-4,6-O-benzylidene-2-deoxy-3-O-mesyl-D-ribo-hex-1-enitol 
• 5987-33-7 4,6-O-benzylidene-D-allal 
• 1135521-22-0 Acetic acid (2R,3S)-2-acetoxymethyl-6-allyl-3,6-dihydro-2H-pyran-3-yl ester 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 95791-07-4 (2R,3S,6R)-6-allyl-2-hydroxymethyl-3,6-dihydro-2H-pyran-3-ol 

Downstream Products

• 115369-31-8 (R)-4-Benzenesulfonyl-1-((4aR,6R,7R,8S,8aR)-7-benzyloxy-8-methoxymethoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl)-7-(tert-butyl-diphenyl-silanyloxy)-6-(1-ethoxy-ethoxy)-heptan-3-one 
• 115369-30-7 (R)-4-Benzenesulfonyl-1-((4aR,6R,7R,8S,8aR)-7-benzyloxy-8-methoxymethoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl)-7-(tert-butyl-diphenyl-silanyloxy)-6-(1-ethoxy-ethoxy)-heptan-3-ol 
• 115352-37-9 C₅₀H₅₈O₈Si 
• 115369-22-7 4-Benzenesulfonyl-1-((4aR,6R,7R,8S,8aR)-7-benzyloxy-8-methoxymethoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl)-6-(tetrahydro-pyran-2-yloxy)-hexan-3-ol 
• 115369-23-8 1-((2R,3R,4R,5R,6R)-3-Benzyloxy-5-hydroxy-6-hydroxymethyl-4-methoxymethoxy-tetrahydro-pyran-2-yl)-6-hydroxy-hexan-3-one 
• 95791-14-3 3-((4aR,6R,7R,8S,8aR)-7-Benzyloxy-8-methoxymethoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl)-propionaldehyde 
• 104307-00-8 C₅₇H₆₄O₈Si 
• 104306-97-0 (R)-1-((4aR,6R,7R,8S,8aR)-7-Benzyloxy-8-methoxymethoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl)-7-(tert-butyl-diphenyl-silanyloxy)-6-(1-ethoxy-ethoxy)-heptan-3-one 
• 95791-16-5 4-Benzenesulfonyl-1-((4aR,6R,7R,8S,8aR)-7-benzyloxy-8-methoxymethoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl)-6-(tetrahydro-pyran-2-yloxy)-hexan-3-one 
• 115369-32-9 (R)-1-((2R,3R,4R,5R,6R)-3-Benzyloxy-5-hydroxy-6-hydroxymethyl-4-methoxymethoxy-tetrahydro-pyran-2-yl)-7-(tert-butyl-diphenyl-silanyloxy)-6-hydroxy-heptan-3-one 
• 104307-01-9 C₃₈H₄₈O₈Si 
• 109413-94-7 C₃₈H₅₀O₈Si 
• 95791-20-1 C₃₇H₄₈O₇Si 
• 95791-17-6 1-((4aR,6R,7R,8S,8aR)-7-Benzyloxy-8-methoxymethoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl)-6-(tetrahydro-pyran-2-yloxy)-hexan-3-one 

Relevant articles and documents

Sc(OTf)3-catalyzed C-glycosidation of glycals: A facile synthesis of allyl glycosides, glycosyl cyanides and glycosyl azides

The treatment of glycals with allyltrimethylsilane, trimethylsilyl cyanide and trimethylsilyl azide in the presence of catalytic amounts of Sc(OTf)3 gave the corresponding 2,3-unsaturated allyl glycosides, glycosyl cyanides and glycosyl azides in excellent yields with high α-selectivity.

SYNTHESIS OF C-GLYCOSYL COMPOUNDS FROM 3,4,6-TRI-O-ACETYL-1,5-ANHYDRO-D-arabino-HEX-1-ENITOL AND ALLYLTRIMETHYLSILANE AND BIS(TRIMETHYLSILYL)ACETYLENE

C-glycosyl derivatives of compounds bearing two, three, or four carbon atoms were obtained from 3,4,6-tri-O-acetyl-1,5-anhydro-D-arabino-hex-1-enitol (1) via a deacetoxylated oxonium ion generated by treatment with a Lewis acid.The nucleophilic reagents w

REACTION OF 4,6-O-BENZYLIDENE-3-O-MESYL-ALLAL WITH ALLYLIC GRIGNARD REAGENTS. HIGHLY REGIO- AND STEREOSELECTIVE PREPARATION OF 2,6-DISUBSTITUTED DIHYDROPYRAN RINGS

The reaction of 4,6-O-benzylidene-1,2-dideoxy-3-O-mesyl-D-ribo-hex-1-enopyranose reacted with 2-propenylmagnesium chloride or 2-methyl-2-propenylmagnesium chloride to give 1,5-anhydro-4,6-O-benzylidene-2,3-dideoxy-1-C-prop-2-enyl- (or 2-methylprop-2-enyl)-β-D-erythro-hex-2-enitol in good yield.