115369-32-9

Basic information

• Product Name: (R)-1-((2R,3R,4R,5R,6R)-3-Benzyloxy-5-hydroxy-6-hydroxymethyl-4-methoxymethoxy-tetrahydro-pyran-2-yl)-7-(tert-butyl-diphenyl-silanyloxy)-6-hydroxy-heptan-3-one
• Synonyms: (R)-1-((2R,3R,4R,5R,6R)-3-Benzyloxy-5-hydroxy-6-hydroxymethyl-4-methoxymethoxy-tetrahydro-pyran-2-yl)-7-(tert-butyl-diphenyl-silanyloxy)-6-hydroxy-heptan-3-one
• CAS NO: 115369-32-9
• Molecular Weight: 680.911
• Mol File: 115369-32-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (R)-1-((2R,3R,4R,5R,6R)-3-Benzyloxy-5-hydroxy-6-hydroxymethyl-4-methoxymethoxy-tetrahydro-pyran-2-yl)-7-(tert-butyl-diphenyl-silanyloxy)-6-hydroxy-heptan-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-1-((2R,3R,4R,5R,6R)-3-Benzyloxy-5-hydroxy-6-hydroxymethyl-4-methoxymethoxy-tetrahydro-pyran-2-yl)-7-(tert-butyl-diphenyl-silanyloxy)-6-hydroxy-heptan-3-one(115369-32-9)
• EPA Substance Registry System: (R)-1-((2R,3R,4R,5R,6R)-3-Benzyloxy-5-hydroxy-6-hydroxymethyl-4-methoxymethoxy-tetrahydro-pyran-2-yl)-7-(tert-butyl-diphenyl-silanyloxy)-6-hydroxy-heptan-3-one(115369-32-9)

Safety Data

• Hazardous Substances Data: 115369-32-9(Hazardous Substances Data)

Upstream product

• 104306-96-9 C₃₀H₃₉O₅SSi^(1-) 
• 95791-08-5 3-((4aR,6R,8aS)-2-Phenyl-4,4a,6,8a-tetrahydro-pyrano[3,2-d][1,3]dioxin-6-yl)-propan-1-ol 
• 95791-10-9 3-((1aS,2R,3aR,7aR,7bS)-6-Phenyl-hexahydro-1,3,5,7-tetraoxa-cyclopropa[a]naphthalen-2-yl)-propan-1-ol 
• 95791-09-6 Benzoic acid 3-((2R,5S,6R)-5-hydroxy-6-hydroxymethyl-5,6-dihydro-2H-pyran-2-yl)-propyl ester 
• 115369-17-0 3-((1aS,2R,3aR,7aR,7bS)-6-Phenyl-hexahydro-1,3,5,7-tetraoxa-cyclopropa[a]naphthalen-2-yl)-propionaldehyde 
• 95791-07-4 (2R,3S,6R)-6-allyl-2-hydroxymethyl-3,6-dihydro-2H-pyran-3-ol 
• 82740-87-2 (2R,3S,6R)-2-acetoxymethyl-6-allyl-3,6-dihydro-2H-pyran-3-yl acetate 
• 104306-97-0 (R)-1-((4aR,6R,7R,8S,8aR)-7-Benzyloxy-8-methoxymethoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl)-7-(tert-butyl-diphenyl-silanyloxy)-6-(1-ethoxy-ethoxy)-heptan-3-one 
• 2873-29-2 D-glucal triacetate 
• 115369-31-8 (R)-4-Benzenesulfonyl-1-((4aR,6R,7R,8S,8aR)-7-benzyloxy-8-methoxymethoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl)-7-(tert-butyl-diphenyl-silanyloxy)-6-(1-ethoxy-ethoxy)-heptan-3-one 
• 115369-30-7 (R)-4-Benzenesulfonyl-1-((4aR,6R,7R,8S,8aR)-7-benzyloxy-8-methoxymethoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl)-7-(tert-butyl-diphenyl-silanyloxy)-6-(1-ethoxy-ethoxy)-heptan-3-ol 
• 115369-29-4 [(R)-4-Benzenesulfonyl-2-(1-ethoxy-ethoxy)-butoxy]-tert-butyl-diphenyl-silane 
• 95791-14-3 3-((4aR,6R,7R,8S,8aR)-7-Benzyloxy-8-methoxymethoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl)-propionaldehyde 
• 88095-33-4 3-(4,6-O-benzylidene-2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl)-1-propene 

Downstream Products

• 109413-94-7 C₃₈H₅₀O₈Si 
• 104307-01-9 C₃₈H₄₈O₈Si 
• 104307-00-8 C₅₇H₆₄O₈Si 
• 115352-37-9 C₅₀H₅₈O₈Si 
• 104307-11-1 C₆₈H₉₂O₁₂ 
• 104307-13-3 tribenzyl okadaic acid 
• 104307-12-2 C₆₅H₈₆O₁₂ 
• 104307-03-1 C₅₇H₇₆O₁₂SSi 
• 104307-07-5 C₅₇H₇₄O₈Si 
• 104307-04-2 C₅₁H₇₀O₁₀Si 
• 104307-05-3 C₅₁H₇₂O₁₀Si 
• 78111-17-8 okadaic acid 
• 104307-09-7 C₄₁H₅₄O₈ 
• 104307-08-6 C₄₁H₅₆O₈ 

Relevant articles and documents

SYNTHESIS OF A MARINE POLYETHER TOXIN, OKADAIC ACID (2) -- SYNTHESIS OF SEGMENT B

The central synthetic segment B for okadaic acid comprises the carbons from 15 through 27 including 6 asymmetric carbons.Its synthesis started from a D-glucose derivative, whose carbon was extended twice for the six and five membered etherial ring formati