881168-34-9Relevant academic research and scientific papers
Stereoselective synthesis of 2,5-di- and 2,2,5-trisubstituted pyrrolidines by allylation reacton of acyliminium ion
Shinada, Tetsuro,Hamada, Makoto,Kawasaki, Masanori,Ohfune, Yasufumi
, p. 511 - 525 (2005)
-Allylation reactions of allytrimethylsilane and an allylcopper reagent to acyliminium ions derived from several 2-monosubstituted and 2,2-disubstituted pyrrolidinones were examined. These reactions proceeded in a stereoselective manner to give the corresponding allylated adducts. The stereochemical outcomes of these reactions were dependent upon the allylating reagents or the structures of the acyliminium ions.
