Heterocycles p. 511 - 525 (2005)
Update date:2022-08-04
Topics:
Shinada, Tetsuro
Hamada, Makoto
Kawasaki, Masanori
Ohfune, Yasufumi
-Allylation reactions of allytrimethylsilane and an allylcopper reagent to acyliminium ions derived from several 2-monosubstituted and 2,2-disubstituted pyrrolidinones were examined. These reactions proceeded in a stereoselective manner to give the corresponding allylated adducts. The stereochemical outcomes of these reactions were dependent upon the allylating reagents or the structures of the acyliminium ions.
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