881423-03-6Relevant articles and documents
Stereocontrolled synthesis and cycloaddition of 1,2,4-trioxygenated 1,3-dienes
Pichon, Nicolas,Harrison-Marchand, Anne,Toupet, Loic,Maddaluno, Jacques
, p. 1892 - 1901 (2006)
A new stereocontrolled synthetic pathway to 1,2,4-trioxygenated 1,3-dienes from pyruvic aldehyde dimethyl acetal (14a) is described. Reacting the cyclohexylamine-derived imine of this starting material with chloroalkyl ethers under basic conditions afford