88155-16-2

Upstream product

• 23339-15-3 ethyl 2,3-dideoxy-α-D-erythro-hex-2-enopyranoside 
• 81303-38-0 Ethyl-4,6-di-O-tosyl-2,3-didesoxy-α-D-erythro-hex-2-enopyranosid 
• 108-24-7 acetic anhydride 
• 81303-42-6 Ethyl-4-azido-2,3,4-tridesoxy-6-O-tosyl-α-D-threo-hex-2-enopyranosid 

Downstream Products

• 88155-18-4 ethyl 4-amino-2,3,4,6-tetradeoxy-α-D-threo-hexopyranoside hydrogen toluene-p-sulphonate 

Relevant academic research and scientific papers

Stereospecific Syntheses of D-Ossamine and D-Tolyposamine

2,3,4,6-Tetradeoxy-4-(dimethylamino)-D-threo-hexose (D-ossamine, 7), the amino sugar fragment from the fungal metabolite ossamycin, and 4-amino-2,3,4,6-tetradeoxy-D-erythro-hexose (D-tolyposamine, 12), the enantiomeric constituent of the antibiotic tolypomycin, have been synthesized from D-glucose via hex-2-enopyranosides.

Synthetic Routes to Amino Sugars. Efficient Syntheses of 4-Amino- and 4,6-Diamino-hexopyranosides and Forosamine via Hex-2-enopyranosides

4-Amino- and 4,6-diamino-hexopyranosides of the threo- and erythro-series have been synthesized from D-glucose via hex-2-enopyranosides.Further work along these lines led to an effective synthesis of forosamine, a 4-deoxy-4-amino sugar moiety of the spira