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[(CO)2Rh(3-(diphenylphosphino)methyl-5-pyridylpyrazolato)Rh(CO)2]BF4 is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 881913-67-3 Structure
  • Basic information

    1. Product Name: [(CO)2Rh(3-(diphenylphosphino)methyl-5-pyridylpyrazolato)Rh(CO)2]BF4
    2. Synonyms: [(CO)2Rh(3-(diphenylphosphino)methyl-5-pyridylpyrazolato)Rh(CO)2]BF4
    3. CAS NO:881913-67-3
    4. Molecular Formula:
    5. Molecular Weight: 747.017
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 881913-67-3.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: [(CO)2Rh(3-(diphenylphosphino)methyl-5-pyridylpyrazolato)Rh(CO)2]BF4(CAS DataBase Reference)
    10. NIST Chemistry Reference: [(CO)2Rh(3-(diphenylphosphino)methyl-5-pyridylpyrazolato)Rh(CO)2]BF4(881913-67-3)
    11. EPA Substance Registry System: [(CO)2Rh(3-(diphenylphosphino)methyl-5-pyridylpyrazolato)Rh(CO)2]BF4(881913-67-3)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 881913-67-3(Hazardous Substances Data)

881913-67-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 881913-67-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 8,8,1,9,1 and 3 respectively; the second part has 2 digits, 6 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 881913-67:
(8*8)+(7*8)+(6*1)+(5*9)+(4*1)+(3*3)+(2*6)+(1*7)=203
203 % 10 = 3
So 881913-67-3 is a valid CAS Registry Number.

881913-67-3Relevant articles and documents

Synthesis of a library of iridium-containing dinuclear complexes with bridging PNNN and PNNP ligands (BL), [LM(μ-BL)M′L′]BF 4. 2. Preparation, basic coordination properties, and reactivity of the carbonyl complexes

Dubs, Christian,Yamamoto, Toshiki,Inagaki, Akiko,Akita, Munetaka

, p. 1359 - 1367 (2006)

A series of dinuclear carbonyl complexes with PNNP and PNNN ligands, [(L)M(PNNX)M′(L)]BF4 (X = P, N; M(L), M′(L′) = Ir(CO)2, Rh(CO)2, Pd(allyl)), have been prepared by carbonylation (1 atm) of the corresponding cod complexes, and the Rh/Ir complexes have been further converted to μ-η1: η2-acetylide complexes, where effective π-back-donation to the acetylide ligand is essential to stabilize them. On the basis of the stability of the acetylide complexes, the π-donating ability of the metal fragment in the PNNX system is estimated to be (P,N)Rh > (P,N)Ir > (N,N)M. The dinuclear PNNX complexes catalyze alkyne hydrogenation, alkene hydroformylation, and allylation of aniline with allyl alcohol, and, for the allylation, a dinuclear mechanism involving activation of allyl alcohol by interaction with a CO ligand is proposed.

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