881920-66-7

Upstream product

• 142921-16-2 (E)-1-iodo-2-methylpent-1-ene 
• 371172-65-5 (E)-tert-butyl(6-iodohex-5-en-1-yloxy)diphenylsilane 
• 627-19-0 1-Pentyne 
• 75-24-1 trimethylaluminum 
• 80434-59-9 (1R,2S,5R)-2-isopropyl-5-methylcyclohexanecarboxaldehyde 

Downstream Products

• 881921-05-7 (9H-fluoren-9-yl)methyl (S,E)-1-((1S,2S,5R)-2-isopropyl-5-methylcyclohexyl)-3-methylhex-1-en-3-ylcarbamate 
• 881920-96-3 (R,E)-1-((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)-3-methylhex-2-enyl carbamate 
• 881920-72-5 (S,E)-1-((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)-3-methylhex-2-enyl carbamate 
• 881920-78-1 (1S,2S,4R)-2-((R,E)-3-isocyanato-3-methylhex-1-enyl)-1-isopropyl-4-methylcyclohexane 
• 881921-02-4 (1S,2S,4R)-2-((S,E)-3-isocyanato-3-methylhex-1-enyl)-1-isopropyl-4-methylcyclohexane 
• 881920-68-9 (R,E)-1-((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)-3-methylhex-2-en-1-ol 
• 920749-95-7 But-3-enoic acid {(R)-1-[(E)-2-((1S,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-vinyl]-1-methyl-butyl}-amide 
• 920749-79-7 But-3-enyl-{(R)-1-[(E)-2-((1S,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-vinyl]-1-methyl-butyl}-amine 
• 920749-77-5 (R)-1-[(E)-2-((1S,2S,5R)-2-Isopropyl-5-methyl-cyclohexyl)-vinyl]-1-methyl-butylamine 
• 881920-82-7 (9H-fluoren-9-yl)methyl (R,E)-1-((1S,2S,5R)-2-isopropyl-5-methylcyclohexyl)-3-methylhex-1-en-3-ylcarbamate 
• 881921-16-0 N-((R,E)-1-((1S,2S,5R)-2-isopropyl-5-methylcyclohexyl)-3-methylhex-1-en-3-yl)acrylamide 
• 881920-90-7 (E)-1-((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)-3-methylhex-2-en-1-one 

Relevant academic research and scientific papers

Efficient preparation of chiral non-racemic sulfur compounds

p-Menthane-3-carboxaldehyde serves as an efficient chiral auxiliary in the preparation of chiral non-racemic S-alkylthiocarbamates or 5-dithiocarbonates via the 3,3-sigmatropic rearrangement of the corresponding alkylthionocarbamates or xanthates. The tra

Cleavage of a chiral auxiliary using RCM on an especially sterically crowded alkene: Syntheses of chiral carbo- and heterocycles

Chiral 1,5-, 1,6-, and 1,7-dienes generated in 3-4 steps from chiral auxiliary p-menthane-3-carboxaldehyde undergo RCM with notable discrepancies in reactivity depending on the nature and number of substituents flanking the central double bond. The chiral

Stereocontrolled formation of amino acids and N-heterocycles bearing a quaternary chiral carbon

Stereocontrolled formation of tertiary or quaternary chiral carbons bearing nitrogen was achieved using the [3,3]-sigmatropic rearrangement of cyanate to isocyanate as a key element. A short and highly selective sequence of reactions, starting from p-ment