881920-82-7Relevant academic research and scientific papers
Stereocontrolled formation of amino acids and N-heterocycles bearing a quaternary chiral carbon
Roy, Stephanie,Spino, Claude
, p. 939 - 942 (2007/10/03)
Stereocontrolled formation of tertiary or quaternary chiral carbons bearing nitrogen was achieved using the [3,3]-sigmatropic rearrangement of cyanate to isocyanate as a key element. A short and highly selective sequence of reactions, starting from p-ment
Cleavage of a chiral auxiliary using RCM on an especially sterically crowded alkene: Syntheses of chiral carbo- and heterocycles
Spino, Claude,Boisvert, Luc,Douville, Jasmin,Roy, Stéphanie,Lauzon, Sophie,Minville, Joannie,Gagnon, David,Beaumier, Francis,Chabot, Christine
, p. 5336 - 5355 (2007/10/03)
Chiral 1,5-, 1,6-, and 1,7-dienes generated in 3-4 steps from chiral auxiliary p-menthane-3-carboxaldehyde undergo RCM with notable discrepancies in reactivity depending on the nature and number of substituents flanking the central double bond. The chiral
