88227-30-9

Downstream Products

• 101215-05-8 (PdCl(NC₅H₄CNCH₃)(P(C₆H₅)3)2) 
• 603-35-0 triphenylphosphine 
• 107653-98-5 [PdCl(C(NC(CH₃)3)C₄H₃N₂)(P(C₆H₅)3)2] 
• 107653-96-3 [PdCl(COC₅H₄N)(P(C₆H₅)3)2] 
• 101215-03-6 (Pd(NC₅H₄)(CNC₆H₄OCH₃)(P(C₆H₅)3)2)⁽¹⁺⁾*ClO₄^(1-)=(Pd(NC₅H₄)(CNC₆H₄OCH₃)(P(C₆H₅)3)2)ClO₄ 
• 101215-10-5 (ZnCl₂(PdCl(NC₅H₄CNC₆H₄OCH₃)((C₆H₅)3P)2)) 
• 101215-07-0 (Pd((CH₃)2NCS₂)(NC₅H₄CNC₆H₄OCH₃)(P(C₆H₅)3)) 
• 101215-04-7 (PdCl(NC₅H₄CNC₆H₄OCH₃)(P(C₆H₅)3)2) 
• 101215-09-2 (PdCl(NC₅H₅CNC₆H₄OCH₃)((C₆H₅)3P)2)⁽¹⁺⁾*ClO₄^(1-)=(PdCl(NC₅H₅CNC₆H₄OCH₃)((C₆H₅)3P)2)ClO₄ 

Relevant academic research and scientific papers

PROTONATION AND METHYLATION REACTIONS OF 2-PYRIDYL-PALLADIUM(II) AND -PLATINUM(II) COMPLEXES

The reactions of strong acids HX and HClO4 with the 2-pyridyl complexes 2, N)(PPh3)>2(X = Cl, Br), trans-2)(PEt3)2> and 2)(dppe)> yield the N-protonated derivatives cis-2)(PPh3)>, trans-2)(PEt3)2>ClO4 and 2)(dpee)>ClO4, respectively.The terminal 2-pyridyl group of trans-2)(PEt3)2> and 2)(dppe)> also reacts with Me2SO4/NaClO4 to give trans-2>(PEt3)2>ClO4 and 2>(dppe)>ClO4.Analogues N-protonation or N-methylation reactions occur with trans-2)(L)2>(L = PEt3, PPh3).The complexes trans-2)(PMe2Ph)2>ClO4(M = Pd, X = Cl and Br; M = Pt, X = Br) exhibit restricted rotation of the protonated 2-pyridyl group around the M-C bond.This and other chemical results and spectral data, such as the 13C NMR data of the PEt3 derivatives, are interpreted in terms of a significant contribution of a carbenelike limiting structure to the electronic configuration of this new type of ligand.