88228-41-5

Upstream product

• 593-75-9 methyl isocyanate 
• 84685-73-4 [Pd₂(C(C₆F₅)N(CH₃))2Cl₂(CNCH₃)2] 

Downstream Products

• 99935-28-1 [Pd(C(C₆F₅)N(CH₃))(CNCH₃)3]⁽¹⁺⁾*B(C₆H₅)4^(1-)=[Pd(C(C₆F₅)N(CH₃))(CNCH₃)3]B(C₆H₅)4 

Relevant academic research and scientific papers

DIVERSE BEHAVIOUR OF IMIDOYL BRIDGES TOWARDS NEUTRAL NUCLEOPHILES: BRIDGE CLEAVAGE, ISONITRILE ELIMINATION, AND FORMATION OF ZWITTERIONIC PALLADIUM COMPLEXES. X-RAY STRUCTURE OF Pd2PdCl2>

Dimeric pentafluoro-N-methylbenzimidoyl-bridged palladium(II) derivatives react with isonitriles to give monomeric, terminal imidoyl complexes, whereas PPh3 causes elimination of methyl isonitrile from the imidoyl group; reaction of Pd2(μ-Cl)2μ-C(C6F5)

TERMINAL PENTAFLUOROBENZIMIDOYLPALLADIUM(II) COMPLEXES. X-RAY STRUCTURE OF trans-Cl(CNMe)2>

The preparations of the complexes trans1)>Cl(CNR2)2> and 1)>(CNR2)2>X (R1= Me, p-Tol; R2= Me, p-Tol, But; X= ClO4 or BPh4) from 1)>2Cl2(CNR2)2> are described.The splitting of the imidoyl bridges is accompained by an isomerization of the imidoyl group from the syn to the anti conformation as shown by a single crystal X-ray diffraction study of trans-Cl(CNMe)2>.Attempted preparations of 1)>Cl(PPh3)2> from 1)>2Cl2(PPh3)2> led to elimination of CNR and formation of trans-; this is the first example of isonitrile elimination in palladium chemistry.