DIVERSE BEHAVIOUR OF IMIDOYL BRIDGES TOWARDS NEUTRAL NUCLEOPHILES: BRIDGE CLEAVAGE, ISONITRILE ELIMINATION, AND FORMATION OF ZWITTERIONIC PALLADIUM COMPLEXES. X-RAY STRUCTURE OF Pd2PdCl2>

DOI: 10.1016/S0022-328X(00)99242-8

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Journal of Organometallic Chemistry p. C47 - C49 (1983)

Update date:2022-08-03

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Authors:

Uson, Rafael

Fornies, Juan

Espinet, Pablo

Lalinde, Elena

Jones, Peter G.

Sheldrick, George M.

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Article abstract of DOI:10.1016/S0022-328X(00)99242-8

Dimeric pentafluoro-N-methylbenzimidoyl-bridged palladium(II) derivatives react with isonitriles to give monomeric, terminal imidoyl complexes, whereas PPh3 causes elimination of methyl isonitrile from the imidoyl group; reaction of < View More

Full text of DOI:10.1016/S0022-328X(00)99242-8

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