88255-58-7

Upstream product

• 7446-70-0 aluminium trichloride 
• 71-43-2 benzene 
• 31469-15-5 1-methoxy-2-methyl-1-trimethylsiloxy-1-propene 
• 98-83-9 isopropenylbenzene 
• 74-88-4 methyl iodide 
• 934-53-2 cumenyl chloride 

Downstream Products

• 859967-21-8 2,2,3-trimethyl-3-phenyl-butyric acid-anhydride 
• 29206-02-8 2,2,3-trimethyl-3-phenylbutanoic acid 

Relevant academic research and scientific papers

Synthesis of alkylbismuths by regiodivergent carbobismuthination of simple alkenes

Switchable regioselectivity: This study represents the first carbobismuthination of alkenes achieved by the treatment of an alkene with a bismuth halide and a ketene silyl acetal. This eaction is particularly noteworthy in that a change in the type of halogen on a bismuth atom very easily switched the regioselectivity (see scheme). Copyright

Lewis Acid-mediated α-tert-Alkylation of Carboxylic Acids and Carboxylic Esters

Carboxylic acids and carboxylic esters can be α-tert-alkylated via the corresponding ketene silyl acetals 2 and 4 using tertiary alkyl halides or acetates in the presence of ZnCl2.The method is successful even if the products are sterically strained due t