882739-48-2 Usage
Uses
Reactant for preparation of:Muramycin analogs as antibacterial agents against drug-resistant bacteriaL-epicapreomycidine using rhodium-catalyzed stereoselective oxidative cyclization(+)-gonyautoxin 3 via Rh-catalyzed amination(+)-monobromophakellin and (+)-phakellin via a strategy applicable to synthesis of more complex members of this family of marine sponge-derived alkaloids including palau′amine2-imidazolidinones and 2-imino-1,3-imidazolidines
Check Digit Verification of cas no
The CAS Registry Mumber 882739-48-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 8,8,2,7,3 and 9 respectively; the second part has 2 digits, 4 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 882739-48:
(8*8)+(7*8)+(6*2)+(5*7)+(4*3)+(3*9)+(2*4)+(1*8)=222
222 % 10 = 2
So 882739-48-2 is a valid CAS Registry Number.
882739-48-2Relevant articles and documents
Catalytic Intramolecular C(sp3)–H Amination of Carbamimidates
Grelier, Gwendal,Rey-Rodriguez, Romain,Darses, Benjamin,Retailleau, Pascal,Dauban, Philippe
, p. 1880 - 1883 (2017)
The RhII-catalyzed intramolecular C(sp3)–H amination of carbamimidates allowed new nitrogen heterocycles to be isolated in yields up to 99 %. The reaction was best performed in the presence of the Rh2(esp)2 (esp = α,α,α′,α′-tetramethyl-1,3-benzenedipropionic acid) complex by using 2,2,2-trichloroethoxysulfonyl-protected compounds. The reaction could be applied to substrates possessing a benzylic, an allylic, a propargylic, or a tertiary C(sp3)–H bond.
