88303-23-5Relevant academic research and scientific papers
Borinic Acid Mediated Hydrosilylations: Reductions of Carbonyl Derivatives
Chardon, Aurélien,Rouden, Jacques,Blanchet, Jér?me
supporting information, p. 995 - 998 (2018/12/13)
4-Fluoro-2-chlorophenylborinic acid acts as a precatalyst in the presence of phenylsilane for the facile reduction of ketones, aldehydes and imines. Notably, synergistic mediation of a tertiary amine was found essential to trigger silicon to boron hydride transfer to generate a key amine–diarylhydroborane Lewis complex.
Silylium ion promoted reduction of imines with hydrosilanes
Muether, Kristine,Mohr, Jens,Oestreich, Martin
supporting information, p. 6643 - 6646 (2014/01/06)
The silylium ion promoted reduction of imines yielding the corresponding amines is reported. Both tert-butylferrocenylmethylsilane and triethylsilane are efficient hydride donors for the reduction of intermediate silyliminium ions, thereby regenerating th
A novel procedure for the synthesis of aziridines: Application of Simmons-Smith reagents to aziridination
Aggarwal, Varinder K,Stenson, Rachel A.,Jones, Ray V.H.,Fieldhouse, Robin,Blacker, John
, p. 1587 - 1589 (2007/10/03)
The reaction of Simmons-Smith carbenoids with imines in the presence of sulfides provides N-(p-toluenesulfonyl)- and N-[(1,1,1-trimethylsilyl)ethyl]sulfonyl-substituted aziridines in high yield.
New Fluorinating Reagents. Part II. Preparation and Synthetic Application of a Saccharin Derived N-Fluorosultam
Differding, Edmond,Lang, Robert W.
, p. 1248 - 1252 (2007/10/02)
The synthesis of the new saccharin derived N-fluorosultam 1 is described.A comparative study with commercially available N-fluorosulfonamides shows 1 to be a superior fluorinating reagent for the synthesis of α-fluorocarbonyl compounds.
